張悅,余(yu)茂(mao)強 摘要:大型天然氣水(shui)蒸(zheng)氣重(zhong)整(zheng)(zheng)制(zhi)氫裝置常用重(zhong)整(zheng)(zheng)爐(lu)(lu)型為(wei)頂燒(shao)爐(lu)(lu)、側燒(shao)爐(lu)(lu)和梯(ti)臺爐(lu)(lu)等。對(dui)3種爐(lu)(lu)型分(fen)別進行介(jie)紹,從(cong)爐(lu)(lu)管(guan)熱量(liang)分(fen)布、結構特點和操作情(qing)況等方(fang)面(mian)進行對(dui)比,并從(cong)爐(lu)(lu)管(guan)材料發展和重(zhong)整(zheng)(zheng)催化劑(ji)進步的角度闡述3種爐(lu)(lu)型的發展趨(qu)勢。 關(guan)鍵詞:天然氣水(shui)蒸(zheng)氣重(zhong)整(zheng)(zheng);重(zhong)整(zheng)(zheng)爐(lu)(lu);制(zhi)氫
發布時間: 2022-09-15 08:39
付(fu)豪,廉紅蕾 摘要:CO2甲(jia)(jia)烷(wan)化(hua)反(fan)應(ying)(ying)(ying)是一(yi)個十分復(fu)雜的(de)多相催化(hua)過程,在(zai)(zai)反(fan)應(ying)(ying)(ying)過程中(zhong)會產生各(ge)種各(ge)樣的(de)中(zhong)間(jian)體(ti),其反(fan)應(ying)(ying)(ying)路徑(jing)目前(qian)還存在(zai)(zai)許多爭(zheng)(zheng)議和矛盾。深入系統地(di)研究(jiu)(jiu)CO2 甲(jia)(jia)烷(wan)化(hua)反(fan)應(ying)(ying)(ying)中(zhong)催化(hua)劑(ji)(ji)表面(mian)(mian)中(zhong)間(jian)體(ti)的(de)演變過程,可以進一(yi)步從機理的(de)角(jiao)度優化(hua)催化(hua)劑(ji)(ji)的(de)設計(ji)方(fang)(fang)案,提高催化(hua)性能。本文主要基于原位(wei)(wei)紅外光譜(pu)表征技術,總(zong)結梳(shu)理了(le)最近關于CO2甲(jia)(jia)烷(wan)化(hua)反(fan)應(ying)(ying)(ying)路徑(jing)研究(jiu)(jiu)的(de)相關工作,著重探討了(le)負載型(xing)催化(hua)劑(ji)(ji)的(de)活性金屬、載體(ti)、助劑(ji)(ji)、合成方(fang)(fang)法(fa)等因素對(dui)CO2甲(jia)(jia)烷(wan)化(hua)反(fan)應(ying)(ying)(ying)路徑(jing)的(de)影響(xiang)以及(ji)由(you)此(ci)對(dui)催化(hua)劑(ji)(ji)性能所產生的(de)積極效果(guo)。同(tong)時(shi)針對(dui)現階段所面(mian)(mian)臨的(de)爭(zheng)(zheng)論點(dian),即反(fan)應(ying)(ying)(ying)氣CO2與H2的(de)活化(hua)位(wei)(wei)點(dian)、催化(hua)劑(ji)(ji)的(de)活性位(wei)(wei)點(dian)以及(ji)未來可行(xing)的(de)研究(jiu)(jiu)方(fang)(fang)法(fa)進行(xing)了(le)詳(xiang)細論述。 關鍵(jian)詞:二氧化(hua)碳甲(jia)(jia)烷(wan)化(hua);反(fan)應(ying)(ying)(ying)路徑(jing);紅外光譜(pu);負載型(xing)催化(hua)劑(ji)(ji)
發布時間(jian): 2022-09-08 08:50
陳德露,安風霞(xia),邵旦(dan)洋(yang),王曉(xiao)佳 摘要(yao)(yao): 生(sheng)(sheng)(sheng)物(wu)(wu)(wu)(wu)質(zhi)是(shi)一(yi)種(zhong)可(ke)再生(sheng)(sheng)(sheng)能(neng)(neng)源,將其作為(wei)(wei)(wei)固體(ti)(ti)(ti)燃料甲(jia)烷(wan)(wan)(wan)化(hua)(hua)(hua)(hua)(hua)(hua),可(ke)以減(jian)少對煤(mei)炭等化(hua)(hua)(hua)(hua)(hua)(hua)石燃料的(de)(de)(de)(de)依賴,也成(cheng)為(wei)(wei)(wei)能(neng)(neng)源消(xiao)(xiao)費結(jie)(jie)(jie)構調整中(zhong)(zhong)天然氣(qi)(qi)生(sheng)(sheng)(sheng)成(cheng)的(de)(de)(de)(de)重要(yao)(yao)途徑(jing)。生(sheng)(sheng)(sheng)物(wu)(wu)(wu)(wu)質(zhi)固廢甲(jia)烷(wan)(wan)(wan)化(hua)(hua)(hua)(hua)(hua)(hua)主要(yao)(yao)有三(san)種(zhong)途徑(jing): 生(sheng)(sheng)(sheng)物(wu)(wu)(wu)(wu)化(hua)(hua)(hua)(hua)(hua)(hua)學(xue)(xue)(xue)轉(zhuan)化(hua)(hua)(hua)(hua)(hua)(hua)途徑(jing)(厭氧(yang)消(xiao)(xiao)化(hua)(hua)(hua)(hua)(hua)(hua))、熱(re)化(hua)(hua)(hua)(hua)(hua)(hua)學(xue)(xue)(xue)轉(zhuan)化(hua)(hua)(hua)(hua)(hua)(hua)途徑(jing)甲(jia)烷(wan)(wan)(wan)化(hua)(hua)(hua)(hua)(hua)(hua)以及結(jie)(jie)(jie)合(he)(he)化(hua)(hua)(hua)(hua)(hua)(hua)學(xue)(xue)(xue)鏈(lian)(lian)(lian)氣(qi)(qi)化(hua)(hua)(hua)(hua)(hua)(hua)技(ji)術的(de)(de)(de)(de)化(hua)(hua)(hua)(hua)(hua)(hua)學(xue)(xue)(xue)鏈(lian)(lian)(lian)甲(jia)烷(wan)(wan)(wan)化(hua)(hua)(hua)(hua)(hua)(hua)。厭氧(yang)消(xiao)(xiao)化(hua)(hua)(hua)(hua)(hua)(hua)工(gong)(gong)(gong)(gong)(gong)藝(yi)(yi)(yi)(yi)(yi)(yi)(yi)(yi)使用微生(sheng)(sheng)(sheng)物(wu)(wu)(wu)(wu)細(xi)菌(jun)將生(sheng)(sheng)(sheng)物(wu)(wu)(wu)(wu)質(zhi)固廢轉(zhuan)為(wei)(wei)(wei)小(xiao)分(fen)子生(sheng)(sheng)(sheng)物(wu)(wu)(wu)(wu),過程(cheng)(cheng)中(zhong)(zhong)可(ke)產(chan)生(sheng)(sheng)(sheng)沼氣(qi)(qi),沼氣(qi)(qi)主要(yao)(yao)由50%~70%的(de)(de)(de)(de)甲(jia)烷(wan)(wan)(wan)和30%~50%的(de)(de)(de)(de)二氧(yang)化(hua)(hua)(hua)(hua)(hua)(hua)碳(tan)組(zu)成(cheng),目(mu)前從(cong)單段消(xiao)(xiao)化(hua)(hua)(hua)(hua)(hua)(hua)池發展到多段多批次消(xiao)(xiao)化(hua)(hua)(hua)(hua)(hua)(hua)系統(tong)。重點介紹了7種(zhong)工(gong)(gong)(gong)(gong)(gong)藝(yi)(yi)(yi)(yi)(yi)(yi)(yi)(yi)流(liu)程(cheng)(cheng),包括Waasa工(gong)(gong)(gong)(gong)(gong)藝(yi)(yi)(yi)(yi)(yi)(yi)(yi)(yi)、Dranco工(gong)(gong)(gong)(gong)(gong)藝(yi)(yi)(yi)(yi)(yi)(yi)(yi)(yi)、Valorga工(gong)(gong)(gong)(gong)(gong)藝(yi)(yi)(yi)(yi)(yi)(yi)(yi)(yi)、Kompogas工(gong)(gong)(gong)(gong)(gong)藝(yi)(yi)(yi)(yi)(yi)(yi)(yi)(yi)、順序分(fen)批厭氧(yang)堆肥(SEBAC)工(gong)(gong)(gong)(gong)(gong)藝(yi)(yi)(yi)(yi)(yi)(yi)(yi)(yi)、厭氧(yang)相態固體(ti)(ti)(ti)(APS)消(xiao)(xiao)化(hua)(hua)(hua)(hua)(hua)(hua)工(gong)(gong)(gong)(gong)(gong)藝(yi)(yi)(yi)(yi)(yi)(yi)(yi)(yi)及久保(bao)田一(yi)體(ti)(ti)(ti)式(shi)厭氧(yang)膜生(sheng)(sheng)(sheng)物(wu)(wu)(wu)(wu)反(fan)(fan)(fan)應(ying)器(KSAMBR)工(gong)(gong)(gong)(gong)(gong)藝(yi)(yi)(yi)(yi)(yi)(yi)(yi)(yi),其中(zhong)(zhong)KSAMBR是(shi)近十年(nian)來發展起來的(de)(de)(de)(de)一(yi)種(zhong)新型工(gong)(gong)(gong)(gong)(gong)藝(yi)(yi)(yi)(yi)(yi)(yi)(yi)(yi),其浸沒式(shi)膜可(ke)保(bao)留產(chan)甲(jia)烷(wan)(wan)(wan)菌(jun),過濾可(ke)溶解的(de)(de)(de)(de)甲(jia)烷(wan)(wan)(wan)發酵抑制(zhi)劑,工(gong)(gong)(gong)(gong)(gong)藝(yi)(yi)(yi)(yi)(yi)(yi)(yi)(yi)過程(cheng)(cheng)穩定、蒸煮器的(de)(de)(de)(de)容積小(xiao)。氣(qi)(qi)化(hua)(hua)(hua)(hua)(hua)(hua)結(jie)(jie)(jie)合(he)(he)甲(jia)烷(wan)(wan)(wan)化(hua)(hua)(hua)(hua)(hua)(hua)工(gong)(gong)(gong)(gong)(gong)藝(yi)(yi)(yi)(yi)(yi)(yi)(yi)(yi)將氣(qi)(qi)化(hua)(hua)(hua)(hua)(hua)(hua)爐和甲(jia)烷(wan)(wan)(wan)化(hua)(hua)(hua)(hua)(hua)(hua)反(fan)(fan)(fan)應(ying)器前后連(lian)接,結(jie)(jie)(jie)合(he)(he)去除硫化(hua)(hua)(hua)(hua)(hua)(hua)物(wu)(wu)(wu)(wu)、氯(lv)化(hua)(hua)(hua)(hua)(hua)(hua)物(wu)(wu)(wu)(wu)、焦油和固體(ti)(ti)(ti)灰等凈化(hua)(hua)(hua)(hua)(hua)(hua)過程(cheng)(cheng),最終獲(huo)得合(he)(he)成(cheng)天然氣(qi)(qi)。介紹了荷蘭(lan)能(neng)(neng)源技(ji)術中(zhong)(zhong)心(ECN)生(sheng)(sheng)(sheng)物(wu)(wu)(wu)(wu)質(zhi)制(zhi)天然氣(qi)(qi)工(gong)(gong)(gong)(gong)(gong)藝(yi)(yi)(yi)(yi)(yi)(yi)(yi)(yi)、德國太陽能(neng)(neng)氫氣(qi)(qi)研究中(zhong)(zhong)心(ZSW)工(gong)(gong)(gong)(gong)(gong)藝(yi)(yi)(yi)(yi)(yi)(yi)(yi)(yi)、瑞士保(bao)羅謝勒研究所(PSI)工(gong)(gong)(gong)(gong)(gong)藝(yi)(yi)(yi)(yi)(yi)(yi)(yi)(yi)等3種(zhong)工(gong)(gong)(gong)(gong)(gong)藝(yi)(yi)(yi)(yi)(yi)(yi)(yi)(yi)流(liu)程(cheng)(cheng)。其中(zhong)(zhong),ECN 生(sheng)(sheng)(sheng)物(wu)(wu)(wu)(wu)質(zhi)制(zhi)天然氣(qi)(qi)工(gong)(gong)(gong)(gong)(gong)藝(yi)(yi)(yi)(yi)(yi)(yi)(yi)(yi)800 kW的(de)(de)(de)(de)中(zhong)(zhong)試(shi)規(gui)模裝置,處理量(liang)(liang)約160 kg/h; ZSW工(gong)(gong)(gong)(gong)(gong)藝(yi)(yi)(yi)(yi)(yi)(yi)(yi)(yi)多管(guan)式(shi)反(fan)(fan)(fan)應(ying)器采用鎳基催化(hua)(hua)(hua)(hua)(hua)(hua)劑,通過熔鹽(yan)多管(guan)熱(re)交換(huan)手(shou)段保(bao)持(chi)反(fan)(fan)(fan)應(ying)器整體(ti)(ti)(ti)溫度在500 ℃左右,可(ke)獲(huo)得含量(liang)(liang)為(wei)(wei)(wei)81.9%的(de)(de)(de)(de)甲(jia)烷(wan)(wan)(wan)氣(qi)(qi)體(ti)(ti)(ti); PSI工(gong)(gong)(gong)(gong)(gong)藝(yi)(yi)(yi)(yi)(yi)(yi)(yi)(yi)采用快速內(nei)循環流(liu)化(hua)(hua)(hua)(hua)(hua)(hua)床,氣(qi)(qi)化(hua)(hua)(hua)(hua)(hua)(hua)反(fan)(fan)(fan)應(ying)溫度為(wei)(wei)(wei)850℃,出(chu)口氣(qi)(qi)體(ti)(ti)(ti)中(zhong)(zhong)CH4含量(liang)(liang)以干氣(qi)(qi)體(ti)(ti)(ti)計(ji)約為(wei)(wei)(wei)9%。化(hua)(hua)(hua)(hua)(hua)(hua)學(xue)(xue)(xue)鏈(lian)(lian)(lian)甲(jia)烷(wan)(wan)(wan)化(hua)(hua)(hua)(hua)(hua)(hua)工(gong)(gong)(gong)(gong)(gong)藝(yi)(yi)(yi)(yi)(yi)(yi)(yi)(yi)將CaO吸附CO2的(de)(de)(de)(de)過程(cheng)(cheng)加入到氣(qi)(qi)化(hua)(hua)(hua)(hua)(hua)(hua)過程(cheng)(cheng)中(zhong)(zhong),免去后續去除CO2工(gong)(gong)(gong)(gong)(gong)藝(yi)(yi)(yi)(yi)(yi)(yi)(yi)(yi),提(ti)高了H/C比(bi),從(cong)而(er)簡化(hua)(hua)(hua)(hua)(hua)(hua)甲(jia)烷(wan)(wan)(wan)化(hua)(hua)(hua)(hua)(hua)(hua)的(de)(de)(de)(de)后處理過程(cheng)(cheng)。基于CaO循環的(de)(de)(de)(de)化(hua)(hua)(hua)(hua)(hua)(hua)學(xue)(xue)(xue)鏈(lian)(lian)(lian)甲(jia)烷(wan)(wan)(wan)化(hua)(hua)(hua)(hua)(hua)(hua)不僅可(ke)以吸收甲(jia)烷(wan)(wan)(wan)化(hua)(hua)(hua)(hua)(hua)(hua)反(fan)(fan)(fan)應(ying)中(zhong)(zhong)的(de)(de)(de)(de)熱(re)量(liang)(liang),同時對生(sheng)(sheng)(sheng)產(chan)過程(cheng)(cheng)的(de)(de)(de)(de)CO2進行封存,將實現碳(tan)的(de)(de)(de)(de)負平衡。該技(ji)術有望在資源化(hua)(hua)(hua)(hua)(hua)(hua)利(li)用生(sheng)(sheng)(sheng)物(wu)(wu)(wu)(wu)質(zhi)固廢方面實現大規(gui)模應(ying)用。研究成(cheng)果為(wei)(wei)(wei)生(sheng)(sheng)(sheng)物(wu)(wu)(wu)(wu)質(zhi)固廢甲(jia)烷(wan)(wan)(wan)化(hua)(hua)(hua)(hua)(hua)(hua)技(ji)術的(de)(de)(de)(de)工(gong)(gong)(gong)(gong)(gong)藝(yi)(yi)(yi)(yi)(yi)(yi)(yi)(yi)選(xuan)擇和設計(ji)提(ti)供參考。 關鍵(jian)詞: 生(sheng)(sheng)(sheng)物(wu)(wu)(wu)(wu)質(zhi); 厭氧(yang)消(xiao)(xiao)化(hua)(hua)(hua)(hua)(hua)(hua); 氣(qi)(qi)化(hua)(hua)(hua)(hua)(hua)(hua); 甲(jia)烷(wan)(wan)(wan)化(hua)(hua)(hua)(hua)(hua)(hua); 化(hua)(hua)(hua)(hua)(hua)(hua)學(xue)(xue)(xue)鏈(lian)(lian)(lian)
發布(bu)時間: 2022-08-31 09:26
王(wang)紅妍 1,馬(ma)(ma)子然(ran) 1,馬(ma)(ma) 靜 1,彭勝攀 1,趙俊平 2,王(wang)寶(bao)冬 1*(1.北(bei)京低碳(tan)清潔能源研究(jiu)(jiu)院,北(bei)京 102211;2.國網能源和(he)(he)豐(feng)煤(mei)(mei)電有(you)限公司,新疆 塔城 834411) 摘(zhai)要:對(dui)(dui)煤(mei)(mei)制(zhi)烯烴行業(ye)(ye)揮(hui)發性有(you)機物(VOCs)的(de)(de)排放(fang)來源和(he)(he)特征(zheng)進行了(le)分析,通過對(dui)(dui)國內外(wai) VOCs 治理(li)技術的(de)(de)研究(jiu)(jiu)和(he)(he)對(dui)(dui)比(bi),結合國內煤(mei)(mei)制(zhi)烯烴企業(ye)(ye)自身的(de)(de)特點,探討了(le)適合的(de)(de) VOCs 治理(li)方案(an),并對(dui)(dui)煤(mei)(mei)制(zhi)烯烴行業(ye)(ye) VOCs 污染處理(li)技術的(de)(de)發展方向進行了(le)展望。 關鍵(jian)詞:煤(mei)(mei)制(zhi)烯烴;揮(hui)發性有(you)機物;控制(zhi)技術;催化燃燒
發布時(shi)間: 2022-08-30 10:08
郭真(zhen)良,卞曉律,杜宇搏,張紋超,姚丁丁,楊海平 摘要(yao)(yao)(yao):開發新型高效的二(er)(er)氧(yang)化(hua)(hua)(hua)碳(tan)捕(bu)集(ji)(ji)或(huo)利(li)用(yong)技(ji)(ji)術(shu)(shu)(shu)對于(yu)減(jian)少化(hua)(hua)(hua)石能(neng)源利(li)用(yong)過程(cheng)的二(er)(er)氧(yang)化(hua)(hua)(hua)碳(tan)排放、緩解全球(qiu)變暖等具有重要(yao)(yao)(yao)意義。集(ji)(ji)成二(er)(er)氧(yang)化(hua)(hua)(hua)碳(tan)捕(bu)集(ji)(ji)與利(li)用(yong)技(ji)(ji)術(shu)(shu)(shu)(ICCU)因其能(neng)耗低和(he)效率高等優勢獲得了廣泛關注。該(gai)技(ji)(ji)術(shu)(shu)(shu)利(li)用(yong)一種雙功能(neng)材(cai)料(liao)通過集(ji)(ji)成二(er)(er)氧(yang)化(hua)(hua)(hua)碳(tan)吸附和(he)原位轉化(hua)(hua)(hua)兩個(ge)主要(yao)(yao)(yao)過程(cheng),實現CO2的高效轉化(hua)(hua)(hua)并(bing)獲得含(han)碳(tan)燃料(liao)。本文(wen)綜述了ICCU中主要(yao)(yao)(yao)技(ji)(ji)術(shu)(shu)(shu)之一集(ji)(ji)成二(er)(er)氧(yang)化(hua)(hua)(hua)碳(tan)捕(bu)集(ji)(ji)與甲(jia)(jia)(jia)烷化(hua)(hua)(hua)轉化(hua)(hua)(hua)。首先對實現該(gai)過程(cheng)的雙功能(neng)材(cai)料(liao)的組成和(he)特性(xing)進行(xing)(xing)概述,緊(jin)接著重點從反(fan)應(ying)溫度(du)、反(fan)應(ying)時(shi)間、反(fan)應(ying)氣體成分等角度(du)探討了影響(xiang)ICCU甲(jia)(jia)(jia)烷化(hua)(hua)(hua)反(fan)應(ying)的因素,并(bing)對該(gai)技(ji)(ji)術(shu)(shu)(shu)未來的機遇和(he)挑戰進行(xing)(xing)總(zong)結和(he)展望,以(yi)期為我國(guo)“雙碳(tan)”目標下致(zhi)力于(yu)二(er)(er)氧(yang)化(hua)(hua)(hua)碳(tan)捕(bu)集(ji)(ji)和(he)利(li)用(yong)的相關研究(jiu)提供一定的借鑒。 關鍵詞:二(er)(er)氧(yang)化(hua)(hua)(hua)碳(tan);捕(bu)集(ji)(ji)與利(li)用(yong);甲(jia)(jia)(jia)烷化(hua)(hua)(hua);雙功能(neng)材(cai)料(liao)
發(fa)布時間: 2022-08-24 09:44
甲(jia)醇(chun)重(zhong)整-氫(qing)燃料(liao)船(chuan)舶案(an)例 之(zhi)前探討(tao)了(le)什么(me)是(shi)(shi)綠色e-甲(jia)醇(chun)及其作(zuo)為(wei)航運燃料(liao)的(de)(de)邏輯和推(tui)動力。關(guan)鍵的(de)(de)一(yi)點(dian)是(shi)(shi)碳(tan)(tan)中性的(de)(de)CO2來(lai)(lai)源(yuan)(yuan),考慮原(yuan)料(liao)來(lai)(lai)源(yuan)(yuan)廣泛性,長遠看(kan)可(ke)能必須采取(qu)空(kong)(kong)氣(qi)直接捕捉(zhuo)DAC,目(mu)前成(cheng)本太高(gao)。生物基(ji)碳(tan)(tan)在推(tui)廣初期比較重(zhong)要,但是(shi)(shi)長遠看(kan)廉(lian)價(jia)生物基(ji)碳(tan)(tan)源(yuan)(yuan)有(you)限。 怎么(me)破(po)?有(you)項目(mu)創(chuang)新性的(de)(de)提(ti)出了(le)一(yi)個貌(mao)似繁瑣但具有(you)可(ke)行性的(de)(de)方案(an),即HyMethShip項目(mu),大致(zhi)流程是(shi)(shi)如下圖,空(kong)(kong)氣(qi)捕捉(zhuo)碳(tan)(tan)+綠氫(qing)合成(cheng)甲(jia)醇(chun)——船(chuan)上甲(jia)醇(chun)水蒸氣(qi)重(zhong)整制氫(qing)+碳(tan)(tan)捕集——氫(qing)提(ti)供動力,碳(tan)(tan)在靠岸的(de)(de)地(di)方卸下來(lai)(lai),用于下一(yi)次合成(cheng)甲(jia)醇(chun)。“首次”航行的(de)(de)碳(tan)(tan)來(lai)(lai)自(zi)空(kong)(kong)氣(qi)捕捉(zhuo),之(zhi)后就依賴自(zi)身系統低(di)成(cheng)本捕捉(zhuo)的(de)(de)碳(tan)(tan)。
發布時間(jian): 2022-08-22 11:37
王希奮,崔富忠,香承志,張永鋒(feng) 摘要:伊犁新天(tian)煤化工(gong)有限公(gong)司是(shi)目(mu)前全(quan)國(guo)最大的煤制(zhi)氣(qi)(qi)項(xiang)目(mu),項(xiang)目(mu)設計(ji)產能20億Nm3/a。甲烷合成(cheng)(cheng)采用(yong)英國(guo)Davy公(gong)司HICOM技術,按(an)A、B兩系(xi)(xi)列設計(ji),每系(xi)(xi)列由甲烷合成(cheng)(cheng)裝置、天(tian)然(ran)(ran)氣(qi)(qi)干(gan)燥裝置、天(tian)然(ran)(ran)氣(qi)(qi)壓(ya)縮(suo)三(san)個裝置組成(cheng)(cheng)。項(xiang)目(mu)在運行(xing)中出現了甲烷合成(cheng)(cheng)循(xun)(xun)環(huan)氣(qi)(qi)壓(ya)縮(suo)機一級密(mi)封氣(qi)(qi)帶水、甲烷合成(cheng)(cheng)系(xi)(xi)統氣(qi)(qi)密(mi)費用(yong)高/耗(hao)(hao)時長、天(tian)然(ran)(ran)氣(qi)(qi)干(gan)燥三(san)甘(gan)醇消耗(hao)(hao)量(liang)高、反應(ying)器壓(ya)差高等一系(xi)(xi)列問題。通過(guo)系(xi)(xi)統優(you)化和(he)各項(xiang)措(cuo)施的實(shi)施,使甲烷合成(cheng)(cheng)兩系(xi)(xi)列能夠保證安全(quan)、穩定、長周期運行(xing)。 關鍵詞:甲烷合成(cheng)(cheng);天(tian)然(ran)(ran)氣(qi)(qi)干(gan)燥;循(xun)(xun)環(huan)氣(qi)(qi)壓(ya)縮(suo)機;天(tian)然(ran)(ran)氣(qi)(qi)壓(ya)縮(suo)機;合成(cheng)(cheng)系(xi)(xi)統氣(qi)(qi)密(mi);汽提(ti)塔
發布時間: 2022-08-10 09:55
吳麗娟,鄭厚超,劉賓元(yuan),熊(xiong)燁(ye) 摘要:二氧化碳化學轉化是當今世界的(de)(de)研(yan)究熱點,以CO2為原(yuan)料可制備高附(fu)加值的(de)(de)綠色聚(ju)合物,為低碳減排(pai)提供了新思(si)路。綜述資(zi)源化利用CO2制備聚(ju)醚碳酸(suan)(suan)酯多元(yuan)醇(chun)(chun)的(de)(de)研(yan)究、工(gong)業(ye)化進(jin)展及(ji)聚(ju)醚碳酸(suan)(suan)酯多元(yuan)醇(chun)(chun)在聚(ju)氨(an)酯產業(ye)中的(de)(de)應用價(jia)值。 關鍵詞(ci):CO2利用;醚聚(ju)碳酸(suan)(suan)酯多元(yuan)醇(chun)(chun);DMC;CO2基多元(yuan)醇(chun)(chun)
發布時(shi)間(jian): 2022-08-04 11:12
劉金(jin)鑫 (沾化(hua)(hua)瑜凱(kai)新材料科技有(you)限公司(si),山(shan)東? 濱州? 256800) 摘(zhai)要:煤(mei)化(hua)(hua)工行業(ye)隨著社會的(de)(de)(de)(de)不(bu)斷發展,得到(dao)了(le)一定程度的(de)(de)(de)(de)改善(shan)、創新、進步,但伴(ban)隨而(er)來的(de)(de)(de)(de)便是對 生(sheng)態(tai)的(de)(de)(de)(de)嚴重破壞。隨著可持續發展戰(zhan)略內容的(de)(de)(de)(de)提出,讓人(ren)們逐(zhu)(zhu)漸開始意識到(dao)生(sheng)存環境的(de)(de)(de)(de)重要性(xing),并(bing)將環保的(de)(de)(de)(de)標(biao)準(zhun)逐(zhu)(zhu)漸提高,在(zai)國家規定的(de)(de)(de)(de)排放(fang)標(biao)準(zhun)內容下(xia),當前(qian)較多企業(ye)使用的(de)(de)(de)(de)化(hua)(hua)工硫回收(shou)裝置已不(bu)能滿足目前(qian)需求(qiu),為此要進行優化(hua)(hua)與創新,促(cu)使其能夠達(da)到(dao)目前(qian)的(de)(de)(de)(de)全新排放(fang)要求(qiu)。基于(yu)此,本文重點分析了(le)脫(tuo)硫工藝的(de)(de)(de)(de)具體(ti)流(liu)程,尾氣(qi)回收(shou)工藝,同時細(xi)致(zhi)闡述了(le)對裝置的(de)(de)(de)(de)改造,供(gong)參考。 關鍵詞(ci) :化(hua)(hua)工硫 ;回收(shou)裝置 ;尾氣(qi)處理(li)
發布時間: 2022-08-03 08:33
瞿(ju) 磊 ,李(li)勝乾 ,江莉莎 摘(zhai)要 陜西延長中(zhong)煤(mei)榆林能源(yuan)(yuan)化(hua)工有限公司(si)180萬t/a煤(mei)-天(tian)然(ran)氣(qi)綜(zong)(zong)合(he)利用(yong)制(zhi)(zhi)(zhi)甲(jia)醇(chun)項(xiang)目利用(yong)了(le)煤(mei)氣(qi)化(hua)“氫少(shao)碳多(duo)”和(he)天(tian)然(ran)氣(qi)轉(zhuan)化(hua)“氫多(duo)碳少(shao)”的(de)特點,實(shi)現了(le)“碳氫互(hu)補”和(he)能源(yuan)(yuan)的(de)綜(zong)(zong)合(he)利用(yong)。介紹了(le)該項(xiang)目的(de)工藝流程,統(tong)(tong)計了(le)系統(tong)(tong)中(zhong)各主要裝置(zhi)CO2的(de)排(pai)(pai)(pai)放(fang)情況,并與傳(chuan)統(tong)(tong)煤(mei)制(zhi)(zhi)(zhi)甲(jia)醇(chun)裝置(zhi)CO2排(pai)(pai)(pai)放(fang)情況進(jin)行(xing)了(le)對(dui)比,結(jie)果(guo)顯(xian)示:煤(mei)-天(tian)然(ran)氣(qi)綜(zong)(zong)合(he)利用(yong)制(zhi)(zhi)(zhi)甲(jia)醇(chun)裝置(zhi)噸甲(jia)醇(chun)CO2排(pai)(pai)(pai)放(fang)量(liang)為0.85t,為傳(chuan)統(tong)(tong)煤(mei)制(zhi)(zhi)(zhi)甲(jia)醇(chun)裝置(zhi)排(pai)(pai)(pai)放(fang)量(liang)的(de)41.3%,較180萬t/a 傳(chuan)統(tong)(tong)煤(mei)制(zhi)(zhi)(zhi)甲(jia)醇(chun)裝置(zhi)CO2減排(pai)(pai)(pai)217.8萬t/a。
發(fa)布時間: 2022-08-01 17:53
醋(cu)酸(suan)(suan)(suan)是一(yi)種重要的(de)(de)有機化(hua)(hua)工原(yuan)料(liao)(liao),其(qi)生(sheng)產方(fang)法主(zhu)要有乙醛氧化(hua)(hua)法、烯烴直接(jie)氧化(hua)(hua)法及甲(jia)醇羰(tang)基(ji)化(hua)(hua)法。乙醛氧化(hua)(hua)法在常壓(ya)、60℃下乙醛的(de)(de)轉(zhuan)(zhuan)化(hua)(hua)率(lv)達到95%,但(dan)因該法所采用的(de)(de)有機汞(gong)催化(hua)(hua)劑(ji)對環境(jing)污(wu)染嚴重,目(mu)前已經(jing)被(bei)逐(zhu)漸(jian)淘(tao)汰;烯烴直接(jie)氧化(hua)(hua)法則因其(qi)原(yuan)料(liao)(liao)(丁(ding)烷、石腦油等(deng))轉(zhuan)(zhuan)化(hua)(hua)率(lv)較低(di)、產品分離工藝復雜、成本(ben)高(gao)等(deng)因素使其(qi)競爭力受到了限制(zhi);甲(jia)醇羰(tang)基(ji)化(hua)(hua)法合(he)成醋(cu)酸(suan)(suan)(suan)的(de)(de)工藝路線具有甲(jia)醇轉(zhuan)(zhuan)化(hua)(hua)率(lv)高(gao)、副(fu)產物(wu)少等(deng)優點,逐(zhu)漸(jian)成為(wei)合(he)成醋(cu)酸(suan)(suan)(suan)的(de)(de)主(zhu)流方(fang)法。由(you)美國(guo)孟山(shan)都(Monsanto) 公(gong)司開發的(de)(de)甲(jia)醇低(di)壓(ya)羰(tang)基(ji)合(he)成醋(cu)酸(suan)(suan)(suan)工藝自20 世紀60 年代末開發投產以(yi)來,目(mu)前已成為(wei)世界生(sheng)產醋(cu)酸(suan)(suan)(suan)的(de)(de)主(zhu)要生(sheng)產方(fang)法。該工藝采用銠的(de)(de)鹵化(hua)(hua)物(wu)為(wei)催化(hua)(hua)劑(ji)、碘甲(jia)烷為(wei)促(cu)進(jin)劑(ji),在壓(ya)力218~310 MPa 和溫度175~185℃下實現了甲(jia)醇和一(yi)氧化(hua)(hua)碳羰(tang)基(ji)合(he)成醋(cu)酸(suan)(suan)(suan)。
發布時間: 2022-07-25 09:49
摘要:介(jie)紹了天(tian)(tian)然(ran)(ran)氣(qi)(qi)脫硫(liu)裝置的(de)(de)工藝流程及國(guo)產(chan)(chan)有機(ji)硫(liu)水(shui)解催(cui)化劑在某(mou)天(tian)(tian)然(ran)(ran)氣(qi)(qi)凈化裝置水(shui)解反(fan)應(ying)器的(de)(de)工業應(ying)用情況。該裝置在負荷分(fen)別為90%,100%,105%的(de)(de)3種工況條件下使用國(guo)產(chan)(chan)有機(ji)硫(liu)水(shui)解催(cui)化劑9個(ge)月后(hou),對有機(ji)硫(liu)水(shui)解催(cui)化劑進(jin)行標定,分(fen)析了水(shui)解反(fan)應(ying)器出口(kou)COS含(han)量、水(shui)解轉化率(lv)及產(chan)(chan)品天(tian)(tian)然(ran)(ran)氣(qi)(qi)組分(fen)變(bian)化情況。結果表明(ming):天(tian)(tian)然(ran)(ran)氣(qi)(qi)中有機(ji)硫(liu)水(shui)解轉化率(lv)大于99.5%,濕凈化天(tian)(tian)然(ran)(ran)氣(qi)(qi)中COS的(de)(de)體積分(fen)數低(di)(di)于1μL/L,產(chan)(chan)品天(tian)(tian)然(ran)(ran)氣(qi)(qi)中硫(liu)化氫的(de)(de)質(zhi)量濃(nong)度低(di)(di)于3mg/m3,總(zong)硫(liu)的(de)(de)質(zhi)量濃(nong)度低(di)(di)于5mg/m3,滿足GB/T17820—2018《天(tian)(tian)然(ran)(ran)氣(qi)(qi)》一類氣(qi)(qi)技術(shu)指(zhi)標,可以(yi)保(bao)障裝置安全穩定運行。
發布時(shi)間(jian): 2022-07-22 09:29